• Re: Will metal salt solutions ruin Peltier (thermoelectric) modules?

    From Y@21:1/5 to Joel Davidson on Mon Mar 13 02:46:07 2023
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    On Sunday, March 12, 2023 at 9:16:03 PM UTC+2, Joel Davidson wrote:
    I've got a real science question, and am hoping that it's visible amidst
    the spam. :-) I'm interested in transferring heat into and out of
    small amounts of aqueous solutions of various metal salts. For the conditions I'm investigating, I think that Peltier (thermoelectric)
    modules are the way to go. Obviously, this will work best when there's
    as little thermal insulation as possible separating the solutions from
    the modules. I could try using very thin glass plates in between the solutions and the modules, with thermal paste. Metal is out of the
    question, due to reaction with the solutes, and something like painted
    metal still risks contamination via a scratch or ionic migration. I
    could try coating the modules with something like a thin layer of
    silicone, or some other coating, I suppose. But what would be most
    efficient would be to simply put the modules directly in contact with
    the solutions.

    But I don't know enough about the material properties of thermoelectric modules to be able to guess if contact with such solutions would make
    them fail. Would metal ions migrate through the ceramic (?) coatings
    and interfere with the semiconductor effects? Are there other potential problems? Obviously, I'm going to be careful to prevent contact between
    the solutions and the conductors that provide power to the modules.

    Thanks!

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