• Lithium Ceramic Batteries

    From Piotr Wyderski@21:1/5 to All on Wed Apr 6 08:00:44 2022
    Hi,

    what might be the expected lifespan of these in a backup application?

    https://media.digikey.com/pdf/Data%20Sheets/TDK%20PDFs/B73180A0101M062_DS.pdf

    Assuming a very low number of charge-discharge cycles, say 10, and
    constant charging, are there any significant degradation mechanisms to
    be taken into account? Given the datasheet doesn't mention that, what
    would be your guess?

    Best regards, Piotr

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  • From jlarkin@highlandsniptechnology.com@21:1/5 to bombald@protonmail.com on Wed Apr 6 07:45:08 2022
    On Wed, 6 Apr 2022 08:00:44 +0200, Piotr Wyderski
    <bombald@protonmail.com> wrote:

    Hi,

    what might be the expected lifespan of these in a backup application?

    https://media.digikey.com/pdf/Data%20Sheets/TDK%20PDFs/B73180A0101M062_DS.pdf

    Assuming a very low number of charge-discharge cycles, say 10, and
    constant charging, are there any significant degradation mechanisms to
    be taken into account? Given the datasheet doesn't mention that, what
    would be your guess?

    Best regards, Piotr

    100 uAH? Why bother? You can get amp-hours of primary lithium that
    will last decades. Or use a supercap.

    The 1812 size is what might make it interesting, but just barely. May
    as well use flash or eeprom.



    --

    I yam what I yam - Popeye

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  • From Piotr Wyderski@21:1/5 to jlarkin@highlandsniptechnology.com on Wed Apr 6 20:53:35 2022
    jlarkin@highlandsniptechnology.com wrote:

    100 uAH? Why bother?

    I have a number of 1uA-ballpark almost always-powered circuit that need
    to operate without interruption. N*100h is plenty, especially that I can
    add N chips like that in parallel/series, as needed. This chip is
    otherwise tailor-made for me, but they don't bother to specify its
    longevity.

    You can get amp-hours of primary lithium that
    will last decades.

    Not really, the self discharge rate is too high for "decades". The best
    thionyl chloride primary cells last as many as 25 years, then even they
    are dead.

    Or use a supercap.

    No hermetic variants available, all drying out. Wet tantalums cannot
    even remotely approach that level of capacitance and they have terrible leakage/self-discharge currents. Not an option.

    May as well use flash or eeprom.

    The circuits are actually doing something, it's not storage backup.
    I'd use FRAM/MRAM for that.

    Best regards, Piotr

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  • From John Larkin@21:1/5 to bombald@protonmail.com on Wed Apr 6 12:21:23 2022
    On Wed, 6 Apr 2022 20:53:35 +0200, Piotr Wyderski
    <bombald@protonmail.com> wrote:

    jlarkin@highlandsniptechnology.com wrote:

    100 uAH? Why bother?

    I have a number of 1uA-ballpark almost always-powered circuit that need
    to operate without interruption. N*100h is plenty, especially that I can
    add N chips like that in parallel/series, as needed. This chip is
    otherwise tailor-made for me, but they don't bother to specify its
    longevity.

    You can get amp-hours of primary lithium that
    will last decades.

    Not really, the self discharge rate is too high for "decades". The best >thionyl chloride primary cells last as many as 25 years, then even they
    are dead.

    The Tadiran parts claim proven 40 year life.




    Or use a supercap.

    No hermetic variants available, all drying out. Wet tantalums cannot
    even remotely approach that level of capacitance and they have terrible >leakage/self-discharge currents. Not an option.

    May as well use flash or eeprom.

    The circuits are actually doing something, it's not storage backup.
    I'd use FRAM/MRAM for that.

    Best regards, Piotr
    --

    If a man will begin with certainties, he shall end with doubts,
    but if he will be content to begin with doubts he shall end in certainties. Francis Bacon

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  • From Piotr Wyderski@21:1/5 to John Larkin on Wed Apr 6 22:54:07 2022
    John Larkin wrote:

    The Tadiran parts claim proven 40 year life.

    Indeed, in their marketing materials. The actual datasheets of the XOL
    line don't go that far. On top of that, they are bulky and solve a
    different problem than mine: they provide energy even when it's not
    needed, i.e. in a typical backup scenario. You have plenty of energy an suddenly you have nothing. So the 100uAh capacity can actually be a lot, provided you can depend on this capacity.

    Best regards, Piotr

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  • From whit3rd@21:1/5 to John Larkin on Wed Apr 6 16:32:56 2022
    On Wednesday, April 6, 2022 at 12:21:35 PM UTC-7, John Larkin wrote:
    On Wed, 6 Apr 2022 20:53:35 +0200, Piotr Wyderski
    <bom...@protonmail.com> wrote:

    jla...@highlandsniptechnology.com wrote:

    You can get amp-hours of primary lithium that
    will last decades.

    Not really, the self discharge rate is too high for "decades". The best >thionyl chloride primary cells last as many as 25 years, then even they
    are dead.

    The Tadiran parts claim proven 40 year life.

    Last year, I replaced a lithium cell (Tadiran) that
    had a 1969 datecode. It failed some time in the last five years,
    as a clock backup.

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  • From DecadentLinuxUserNumeroUno@decadenc@21:1/5 to jlarkin@highlandsniptechnology.com on Thu Apr 7 14:50:17 2022
    jlarkin@highlandsniptechnology.com wrote in news:ai9r4h9ndlnhfkd056f8372i2b6huc0pod@4ax.com:

    On Wed, 6 Apr 2022 08:00:44 +0200, Piotr Wyderski
    <bombald@protonmail.com> wrote:

    Hi,

    what might be the expected lifespan of these in a backup
    application?

    https://media.digikey.com/pdf/Data%20Sheets/TDK%20PDFs/B73180A0101M >>062_DS.pdf

    Assuming a very low number of charge-discharge cycles, say 10, and
    constant charging, are there any significant degradation
    mechanisms to be taken into account? Given the datasheet doesn't
    mention that, what would be your guess?

    Best regards, Piotr

    100 uAH? Why bother? You can get amp-hours of primary lithium that
    will last decades. Or use a supercap.

    The 1812 size is what might make it interesting, but just barely.
    May as well use flash or eeprom.

    Sodium Ion is supposed to be the next battery technology.

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