• What may be IUPAC name of two cyclo-alkane/Benzene rings passing throug

    From joshipura@gmail.com@21:1/5 to All on Thu Jul 16 20:54:04 2020
    Hello,

    I am no chemist. So, apology in advance for anything nonsense posted here.

    However, while discussing IUPAC naming with my high school junior son, I came across this idea, which is conceivable, may not always be possible.

    Quickest imagination is two Benzene rings passing through each other. Behavior of this molecule may be significantly different from two Benzene rings.
    The idea can be extended to any two or more cyclical molecules.
    To make the matter worse, we can think of any entanglement of various rings, not necessary a linear chain.
    It may end up in meta-catanation of rings.

    It isn't exactly an stereoisomer of Benzene/cyclo-alkane because it is an isomer of *two* (or more) molecules instead of one.
    (I hope you are with me so far.)

    Question 1: How are such chemicals named?
    Question 2: What do you call such a condition?
    Question 3: Are such chemicals known?

    Thanks in advance,
    -Bhushit

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  • From Ian Gay@21:1/5 to joshipura@gmail.com on Thu Jul 16 23:26:03 2020
    joshipura@gmail.com wrote:

    Hello,

    I am no chemist. So, apology in advance for anything nonsense posted
    here.

    However, while discussing IUPAC naming with my high school junior son,
    I came across this idea, which is conceivable, may not always be
    possible.

    Quickest imagination is two Benzene rings passing through each other. Behavior of this molecule may be significantly different from two
    Benzene rings. The idea can be extended to any two or more cyclical molecules. To make the matter worse, we can think of any entanglement
    of various rings, not necessary a linear chain. It may end up in meta-catanation of rings.

    It isn't exactly an stereoisomer of Benzene/cyclo-alkane because it is
    an isomer of *two* (or more) molecules instead of one.
    (I hope you are with me so far.)

    Question 1: How are such chemicals named?
    Question 2: What do you call such a condition?
    Question 3: Are such chemicals known?

    Thanks in advance,
    -Bhushit

    See wikipedia article on "catenane". It won't happen with any ring as
    small as benzene.

    Ian

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  • From joshipura@gmail.com@21:1/5 to All on Fri Jul 17 00:03:32 2020
    Thanks. That is really educative.

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