"In 2000, a simple, foundational thermodynamic paradox was proposed: a sealed blackbody cavity contains a diatomic gas and a radiometer whose apposing vane surfaces dissociate and recombine the gas to different degrees (A_2 ⇌ 2A). As a result of
differing desorption rates for A and A_2 , there arise between the vane faces permanent pressure and temperature differences, either of which can be harnessed to perform work, in apparent conflict with the second law of thermodynamics. Here we report on
the first experimental realization of this paradox, involving the dissociation of low-pressure hydrogen gas on high-temperature refractory metals (tungsten and rhenium) under blackbody cavity conditions. The results, corroborated by other laboratory
studies and supported by theory, confirm the paradoxical temperature difference and point to physics beyond the traditional understanding of the second law."
https://link.springer.com/article/10.1007/s10701-014-9781-5
"A simple device is introduced that utilizes the phenomenon of epicatalysis to establish a stationary temperature difference by which ambient environmental thermal energy might be converted into useful work. [...] Traditional catalysis is a central pivot
around which much of the industrial and biological worlds turn. Positive catalysts satisfy three general principles. First, they increase reaction rates by providing lower activation energies for rate-limiting steps. Second, they are not consumed by
their net reactions although they are intimately involved in them. Third, they do not alter final thermodynamic equilibria of their reactions. Epicatalysts bend this third principle in that they shift the final gas-phase equilibria of reactions." D. P.
Sheehan, T. M. Welsh, Epicatalytic thermal diode: Harvesting ambient thermal energy, Sustainable Energy Technologies and Assessments, Volume 31, February 2019, Pages 355-368
https://www.sciencedirect.com/science/article/pii/S2213138818301838
There is no separate group of "epicatalysts" - actually all catalysts shift the equilibrium and so violate the second law of thermodynamics (even though in most cases the effect is difficult to detect). Here is a catalyst that speeds up the forward
reaction, 2H+ → H_2, but SUPPRESSES the reverse reaction, H_2 → 2H+ (violation of the second law of thermodynamics par excellence):
Yu Hang Li et al. Unidirectional suppression of hydrogen oxidation on oxidized platinum clusters
https://www.nature.com/articles/ncomms3500
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Pentcho Valev
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