Comet 67P's abundant oxygen more of an illusion, new study suggests


Date:
March 14, 2022
Source:
Johns Hopkins University Applied Physics Laboratory
Summary:
When the European Space Agency's Rosetta spacecraft
discovered abundant molecular oxygen bursting from comet
67P/Churyumov-Gerasimenko (67P) in 2015, it puzzled scientists. They
had never seen a comet emit oxygen, let alone in such abundance. But
most alarming were the deeper implications: that researchers
had to account for so much oxygen, which meant reconsidering
everything they thought they already knew about the chemistry of
the early solar system and how it formed. A new analysis, however,
shows Rosetta's discovery may not be as strange as scientists first
imagined. Instead, it suggests the comet has two internal reservoirs
that make it seem like there's more oxygen than is actually there.



FULL STORY ==========================================================================
When the European Space Agency's Rosetta spacecraft discovered abundant molecular oxygen bursting from comet 67P/Churyumov-Gerasimenko (67P)
in 2015, it puzzled scientists. They had never seen a comet emit
oxygen, let alone in such abundance. But most alarming were the deeper implications: that researchers had to account for so much oxygen, which
meant reconsidering everything they thought they already knew about the chemistry of the early solar system and how it formed.


==========================================================================
A new analysis, however, led by planetary scientist Adrienn Luspay-Kuti at
the Johns Hopkins Applied Physics Laboratory (APL) in Laurel, Maryland,
shows Rosetta's discovery may not be as strange as scientists first
imagined.

Instead, it suggests the comet has two internal reservoirs that make it
seem like there's more oxygen than is actually there.

"It's kind of an illusion," Luspay-Kuti said. "In reality, the comet
doesn't have this high oxygen abundance, at least not as far as its
formation goes, but it has accumulated oxygen that gets trapped in
the upper layers of the comet, which then gets released all at once."
While common on Earth, molecular oxygen (two oxygen atoms doubly linked
to each other) is markedly uncommon throughout the universe. It quickly
binds to other atoms and molecules, especially the universally abundant
atoms hydrogen and carbon, so oxygen appears only in small amounts in
just a few molecular clouds.

That fact led many researchers to conclude any oxygen in the protosolar
nebula that formed our solar system likely had been similarly scooped up.

When Rosetta found oxygen pouring out of comet 67P, however, everything
turned on its head. Nobody had seen oxygen in a comet before, and as the
fourth most abundant molecule in the comet's bright coma (after water,
carbon dioxide and carbon monoxide), it needed some explanation. The
oxygen seemed to come off the comet with water, causing many researchers
to suspect the oxygen was either primordial -- meaning it got tied up
with water at the birth of the solar system and amassed in the comet
when it later formed -- or formed from water after the comet had formed.

But Luspay-Kuti and her team were skeptical. As the comet's dumbbell shape gradually rotates, each "bell" (or hemisphere) faces the Sun at various
points, meaning the comet has seasons so the oxygen-water connection
might not be present all the time. On short time frames, volatiles could potentially turn on and off as they thaw and refreeze with the seasons.



==========================================================================
Now You See It, Now You Don't Taking advantage of these seasons, the
team examined the molecular data on short- and long-time periods just
before the comet's southern hemisphere entered summer and then again
just as its summer ended. As reported in their study, published March
10 in Nature Astronomy, the team found that as the southern hemisphere
turned away and was sufficiently far from the Sun, the link between
oxygen and water disappeared. The amount of water coming off the comet
dropped precipitously, so instead the oxygen seemed strongly linked to
carbon dioxide and carbon monoxide, which the comet was still emitting.

"There's no way that should be possible under the previous explanations suggested," Luspay-Kuti said. "If oxygen were primordial and tied to
water in its formation, there shouldn't be any time that oxygen strongly correlates with carbon monoxide and carbon dioxide but not water."
The team instead proposed the comet's oxygen doesn't come from water
but from two reservoirs: one made of oxygen, carbon monoxide and carbon
dioxide deep inside the comet's rocky nucleus, and a shallower pocket
closer to the surface where oxygen chemically combines with water ice molecules.

The idea goes like this: A deep reservoir of oxygen, carbon monoxide and
carbon dioxide ice is constantly emitting gases because oxygen, carbon
dioxide and carbon monoxide all vaporize at very low temperatures. As
oxygen traverses from the comet's interior toward the surface, however,
some chemically inserts into water ice (a major constituent of the
comet's nucleus) to form a second, shallower oxygen reservoir. But water
ice vaporizes at a much higher temperature than oxygen, so until the Sun sufficiently heats the surface and vaporizes the water ice, the oxygen
is stuck.



==========================================================================
The consequence is that oxygen can accumulate in this shallow reservoir
for long periods until the comet surface is finally warmed enough for
water ice to vaporize, releasing a plume far richer in oxygen than was
actually present in the comet.

"Put another way, the oxygen abundances measured in the comet's coma
aren't necessarily reflecting its abundances in the comet's nucleus," Luspay-Kuti explained.

The comet would consequently also vacillate with the seasons between
strongly associating with water (when the Sun heats the surface) and
strongly associating with carbon dioxide and carbon monoxide (when that
surface faces away from the Sun and the comet is sufficiently far) --
exactly what Rosetta observed.

"This isn't just one explanation: It's the explanation because there is
no other possibility," said Olivier Mousis, a planetary scientist from
France's Aix-Marseille Universite' and a study co-author. "If oxygen were
just coming from the surface, you wouldn't see these trends observed by Rosetta." The major implication, he said, is that it means comet 67P's
oxygen is, in fact, oxygen that accreted at the beginning of the solar
system. It's just that it's only a fraction of what people had thought.

Luspay-Kuti said she wants to probe the topic more deeply by examining
the comet's minor molecular species, such as methane and ethane, and
their correlation with molecular oxygen and other major species. She
suspects this will help researchers get a better idea of the type of
ice that the oxygen was incorporated into.

"You still have to come up with a way to incorporate the oxygen into the comet," Luspay-Kuti said, considering that the amount of oxygen is still
higher than seen in most molecular clouds. But she said she expected a
majority of researchers will welcome the study and its conclusions with
a sigh of relief.


========================================================================== Story Source: Materials provided by Johns_Hopkins_University_Applied_Physics_Laboratory.

Original written by Jeremy Rehm. Note: Content may be edited for style
and length.


========================================================================== Related Multimedia:
* Comet_67P/Churyumov-Gerasimenko ========================================================================== Journal Reference:
1. Adrienn Luspay-Kuti, Olivier Mousis, Franc,oise Pauzat, Ozge
Ozgurel,
Yves Ellinger, Jonathan I. Lunine, Stephen A. Fuselier, Kathleen E.

Mandt, Karlheinz J. Trattner, Steven M. Petrinec. Dual
storage and release of molecular oxygen in comet
67P/Churyumov-Gerasimenko. Nature Astronomy, 2022; DOI:
10.1038/s41550-022-01614-1 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2022/03/220314154420.htm

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