• Safer, more powerful batteries for elect

    From ScienceDaily@1:317/3 to All on Mon Mar 7 21:30:48 2022
    Safer, more powerful batteries for electric cars, power grid
    Solid-state batteries with little liquid electrolyte are safer than lithium-ion batteries

    Date:
    March 7, 2022
    Source:
    DOE/Sandia National Laboratories
    Summary:
    A new study tackled a long-held assumption that adding some
    liquid electrolyte to improve performance would make solid-state
    batteries unsafe. Instead, the research team found that in many
    cases solid-state batteries with a little liquid electrolyte were
    safer than their lithium- ion counterparts. They also found, if the
    battery were to short-circuit, releasing all its stored energy,
    the theoretically super-safe, all-solid- state battery could put
    out a dangerous amount of heat.



    FULL STORY ========================================================================== Solid-state batteries, currently used in small electronic devices like
    smart watches, have the potential to be safer and more powerful than lithium-ion batteries for things such as electric cars and storing energy
    from solar panels for later use. However, several technical challenges
    remain before solid-state batteries can become widespread.


    ==========================================================================
    A Sandia National Laboratories-led study, published on March 7 in the scientific journal Joule, tackled one of these challenges -- a long-held assumption that adding some liquid electrolyte to improve performance
    would make solid-state batteries unsafe. Instead, the research team
    found that in many cases solid-state batteries with a little liquid
    electrolyte were safer than their lithium-ion counterparts. They also
    found, if the battery were to short-circuit, releasing all its stored
    energy, the theoretically super-safe, all-solid-state battery could put
    out a dangerous amount of heat.

    "Solid-state batteries have the potential to be safer, and they have
    the potential for higher energy density," said Alex Bates, a Sandia postdoctoral researcher who led the study for the paper. "This means,
    for electric vehicles, you could go farther in between charges, or need
    fewer batteries for grid-scale energy storage. The addition of liquid electrolyte may help bridge the gap to commercialization, without
    sacrificing safety." Better batteries through chemistry Solid-state
    batteries are somewhat like lithium-ion batteries. In both, lithium
    ions move from one side of the battery to the other, while electrons
    flow through a circuit to power the device. One big difference is that throughout a lithium-ion battery, there is a substance that helps the
    lithium ions move quickly: the liquid electrolyte.

    Loraine Torres-Castro, a battery safety expert in Sandia's Battery Abuse Testing Laboratory who is involved in the project, compares liquid
    electrolyte to a fleet of cars pulling into driveways: It shuttles
    lithium ions directly where they need to go. However, current liquid electrolytes are flammable and can cause a battery explosion or fire, especially when the battery is damaged.



    ==========================================================================
    In a solid-state battery, the liquid electrolyte is replaced by a solid material, called a solid electrolyte, that also helps the lithium ions
    move quickly. One technical challenge is that while the lithium ions
    can move quickly within the solid electrolyte, they have a hard time
    moving from the solid electrolyte to the electrodes and vice versa,
    Bates said. The solid electrolyte could be compared to a cadre of trains,
    also quickly shuttling the lithium ions to the station, but then the
    passengers still have to travel a bit farther to get home.

    One way scientists have sped up this "direct shuttling" -- and thus
    battery charging speeds and performance -- is by adding a little bit of
    liquid electrolyte to the positive side of the battery.

    However, Yuliya Preger, a Sandia battery reliability expert on the
    project, said, "There has been a lot of controversy in the solid-state
    battery research community about the safety of including liquid
    electrolyte to 'grease the wheels.' Some scientists say that any amount
    of liquid electrolyte is unsafe.

    So, we did the calculations to see what the impacts of liquid electrolyte
    could be, instead of just accepting the 'party line.'" Steve Harris,
    a battery scientist at Lawrence Berkeley National Laboratory, and Katie Harrison, a Sandia battery scientist, first questioned the 'party line'
    that led to the study. Both were involved in the study.

    How safe are solid-state batteries? In order to figure out just how
    safe a solid-state battery with a little liquid electrolyte would be,
    the research team started by calculating how much heat could be released
    in a lithium-ion battery, an all solid-state battery and solid-state
    batteries with varying amounts of liquid electrolyte. All batteries
    tested had equivalent amounts of stored energy. Then, they looked at
    three different bad things that could happen to the batteries, and the
    heat that would be released due to each type of failure.



    ==========================================================================
    "We started by determining just how much chemical energy is in the three
    kinds of batteries," said John Hewson, a Sandia heat-release calculation
    expert on the project. "There's only so much energy you can release,
    which will heat up the battery a certain amount, if a chemical reaction
    does occur." The first bad thing that could happen is if the batteries
    caught on fire - - from either a neighboring battery or a surrounding
    building -- Torres-Castro said. In these cases, the researchers found that
    the solid-state battery with a little liquid electrolyte in it produced
    about one-fifth of the heat of a comparable lithium-ion battery --
    depending on how much liquid electrolyte it had. The solid-state battery without liquid electrolyte didn't produce any heat under this scenario.

    The second bad thing that could happen to the batteries is if repeated
    charging and discharging caused the lithium metal to form a "spike"
    called a dendrite.

    This dendrite can puncture a hole through the separator that keeps the
    two sides distinct and causes a short-circuit, Preger said. This is a
    known issue with all batteries that have lithium metal on one side. In
    this case, all three batteries produced similar amounts of heat, which
    depended on how much lithium metal was in the batteries.

    The third bad thing that could happen to a solid-state battery is
    the solid electrolyte could break. This could happen if the battery
    was crushed or punctured or due to built-up pressure during operation,
    which would allow oxygen from one side of the battery to react with the
    lithium metal on the other side, Torres-Castro said. In these cases, the solid-state battery without liquid electrolyte could reach temperatures
    near that of the lithium-ion battery, which the team found surprising.

    From safety calculations to laboratory experiments "One of the promises of solid-state batteries is that they are safe because the solid electrolyte
    is firm and unlikely to break. But if it does break, the temperature
    rise could be about as much as when lithium-ion batteries fail," Preger
    said. "This study highlighted the importance of engineering the heck
    out of that separator so that it does not fail." The next steps for
    the project include conducting similar calculations with other solid electrolyte materials and conducting experiments to validate the new
    and original calculations, Bates said.

    "We found if the solid-state battery has lithium metal, it has the
    potential to be dangerous, regardless of if it has liquid electrolyte
    or not," he said.

    "What we were trying to point out in this paper is that there's a definite trade-off between performance and safety, but adding a bit of liquid may greatly increase performance while only having a small impact on safety." Understanding this trade-off may help speed up commercialization,
    Torres-Castro added. "Having the clarity and the confidence that knowing a small amount of liquid electrolyte will not create huge safety issues may
    help the development of commercial solid-state batteries. Adding liquid electrolyte could fix one of their main problems, the solid electrolyte interface." This safety study was supported by the Department of Energy's Office of Electricity Energy Storage Program.

    ========================================================================== Story Source: Materials provided by
    DOE/Sandia_National_Laboratories. Note: Content may be edited for style
    and length.


    ========================================================================== Journal Reference:
    1. Alex M. Bates, Yuliya Preger, Loraine Torres-Castro, Katharine L.

    Harrison, Stephen J. Harris, John Hewson. Are solid-state
    batteries safer than lithium-ion batteries? Joule, 2022; DOI:
    10.1016/j.joule.2022.02.007 ==========================================================================

    Link to news story: https://www.sciencedaily.com/releases/2022/03/220307113014.htm

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